Application of Buehler

Decision Date22 May 1975
Docket NumberNo. 74-613.,74-613.
Citation515 F.2d 1134
PartiesApplication of William J. BUEHLER.
CourtU.S. Court of Customs and Patent Appeals (CCPA)

Paul M. Craig, Jr., Washington, D. C., attorney of record, for appellant.

Joseph F. Nakamura, Washington, D. C., for the Commissioner of Patents, Henry W. Tarring, II, Washington, D. C., of counsel.

Before MARKEY, Chief Judge, and RICH, BALDWIN, LANE and MILLER, Judges.

LANE, Judge.

This appeal is from the decision of the Patent and Trademark Office Board of Appeals affirming the rejection of all claims (8-14 and 23-28) in appellant's patent application serial No. 788,135, filed December 31, 1968, for "Method and Apparatus for Continuously Casting Wire or the Like." All claims were rejected on two grounds: (1) obvious subject matter under 35 U.S.C. § 103, and (2) double patenting of the "obviousness-type" wherein no terminal disclaimer has been filed. We reverse.

The Invention

Appellant's invention pertains to a method of continuously casting 55-Nitinol,1 which is a specific titanium-nickel (Ti-Ni) alloy, into relatively small wire or flat ribbon shapes. According to appellant's brief, 55-Nitinol is a stoichiometric alloy possessing high ductility and other properties as follows:

55-Nitinol has many unique properties among which is its total non-magnetic characteristic, its non-corrosive characteristic and, above all, its ability to convert heat into mechanical energy. If, for example, a thin wire of 55-Nitinol is deformed below its transition temperature and is then heated through its transition temperature, it will revert to its original shape with simultaneous release of mechanical energy.

The apparatus2 employed in appellant's method is illustrated by Fig. 2 in the specification:

Claim 23 is the sole independent claim (bracketed matter and reference numerals added):

23. A method for continuously casting molten TiNi-base alloys having of the order of 55% by weight of Ni into relatively small wire or relatively flat ribbon shapes by the use of a graphite crucible 11 directly adjoined by a metal die body 15 provided with a shape-forming orifice 18 comprising the steps of
a melting by means of high frequency heating coils 70 the alloy in the graphite crucible within a non-contaminating environment utilizing the graphite crucible as susceptor for the TiNi-base alloy,
b cooling by means of water in water passages 16 in metal die body 15 at least a part of the metal die body while forcing the molten alloy through its shape forming orifice 18, and
c continuously removing the cast alloy from the die.

The dependent claims add specific recitals of an evacuated environment, an inert gas, heating the crucible while cooling the die, controlling heating and cooling to develop a temperature gradient, using an ingot of the alloy, initially forming a solid skull of alloy, and insertion of a stop plug into the die orifice.

Appellant's brief contains the following statement:

A few words concerning the historical development of the present invention is also believed desirable to place the same into proper perspective. Initially, the TiNi base alloys were made by the use of consumable or non-consumable are casting, a method which had been successfully developed and applied in processing titanium. Since both nickel and titanium are highly reactive with various elements, including carbon, it was deemed impossible to use a graphite crucible in connection with making the alloy. However, in the course of further work, appellant discovered that though both the elemental components of Ti and Ni were each highly reactive with carbon and graphite, the alloy itself consisting essentially of these two elemental components was totally inert or nonreactive with carbon and graphite. This suggested to appellant the possibility that a graphite crucible might be used for making the alloy from its elemental components if a pre-alloyed material of the TiNi-alloy to be obtained is first placed into the graphite crucible, is then melted and the elemental components of TiNi are thereupon charged into the molten alloy while substantially preventing direct contact between the elemental component metals and the crucible walls. This approach proved successful and is the one described in appellant's U.S. Patent 3,529,958, which permitted the use of a graphite crucible in making the alloy from its elemental components of Ti & Ni, thereby obviating the inferior arc-casting process used hitherto which could not insure the necessary homogeneity of the ingot for products such as wires with identical properties, a prerequisite in view of the effect of impurities or non-homogeneities on the transition temperature of the 55 Nitinol. Footnotes omitted.

Appellant emphasizes the fact that the claimed method requires the use of a graphite crucible which acts as a susceptor for the TiNi-base alloy. His specification employs the term "susceptor" in this way:

By being able to melt the alloy in a graphite crucible which represents excellent susceptor characteristics, it is possible to control the alloy temperature with sufficient precision in the crucible and in its passage through the graphite die-body to allow the formation and solidification of the wire. Emphasis ours.

Appellant's specification also contains the following statements relevant to the use of a graphite crucible:

Continuous casting methods of copper-base-type alloys are known in the prior art (U.S. Patents 2,136,394 and 2,782,473). However, these methods and apparatus are not suitable for continuously casting a wire of a TiNi alloy, containing approximately 45% by weight of titanium, which in its elemental form is normally highly reactive, in particular with graphite.
* * * * * *
An additional feature of the present invention is to be able to melt in a graphite crucible which constitutes a good susceptor in order to control the alloy temperature with such precision as to allow formation and solidification of the wire . . .. Normally, few medium temperature structure alloys are sufficiently inert in graphite, and certainly the iron base alloys and nickel base alloys are completely reactive with graphite.

Prior to the instant invention, the art knew that stoichiometric TiNi alloys could be made into wire by hot-rolling an ingot into a bar, hot-swaging the bar into a rod and then wire-drawing the rod. However, such prior art method of making TiNi wire is relatively uneconomical and does not permit continuous production of the wire in any desired length.

The References

The examiner and the board relied on five prior art references:

                  (1)  Clark            3,598,168  Aug. 10, 1971
                                                   (Filed Oct. 14, 1968)
                  (2)  Eldred           2,242,350  May 20, 1941
                  (3)  Heraeus            440,859  Jan. 7, 1936
                       (Great Britain)
                  (4)  Howard et al.    1,013,851  Dec. 22, 1965
                       (Great Britain)
                  (5)  Buehler et al.   3,174,851  March 23, 1965
                

The examiner and the board cited the claims of another reference for the purpose of establishing double patenting of the "obviousness-type":

                       Buehler          3,529,958  Sept. 22, 1970
                                                   (Filed Nov. 4, 1966)
                

It should be noted that Buehler is not a prior art reference under 35 U.S.C. §§ 102 or 103. Furthermore, this Buehler patent (Buehler) should not be confused with the Buehler et al. patent (Buehler et al.), which is a prior art reference.

The Rejections

The examiner rejected claims 8-14 and 23-28 under 35 U.S.C. § 103 as being "unpatentable over" Clark in view of Eldred, Heraeus, Howard et al. and Buehler et al. The board sustained this rejection and stated:

We find that the differences between the prior art and the process of the appealed claims are such differences as would be obvious to one skilled in the art armed with the disclosure of the applied references. Emphasis ours.

The examiner also rejected claims 8-14 and 23-28 "under the judicially-created doctrine of `obviousness-type' double patenting over" the claims of Buehler in view of Eldred, Heraeus, and Howard et al. The board stated:

Since we agree with the examiner that the presently claimed process is but an obvious variation, in the double patenting rather than in the 35 U.S.C. § 103 sense, of the process already called for by Buehler and, on the present record, is not allowable in view of the prior art, we will sustain the examiner's rejection.
Clark

The Clark prior art patent, entitled "Titanium Casting Process," discloses a method and apparatus for batch casting. In his "Description of the Prior Art," Clark states:

Titanium alloys used in forming shaped castings are usually skull melted in water-cooled, crucible arc melting units. The temperature control in this type of melting is difficult because the molten titanium is cooled rapidly by the water-cooled crucible when power from the are is terminated. A resulting variation in pouring temperature may cause many casting defects. If the temperature is too high, dimensional and metallurgical problems result. If the pouring temperature is too low, the castings misrun and also contain metallurgical defects.
One of the most serious problems in melting and pouring titanium is the avoidance of contamination. Titanium has a strong affinity for hydrogen, nitrogen, oxygen and carbon. Excess absorbed hydrogen is removed from titanium alloys by expensive processing such as vacuum annealing. According to current specifications, the hydrogen content of titanium should be limited to about 125 and 200 parts per million. Above these limits, hydrogen embrittles most titanium alloys, and reduces their impact strength and notch tensile strength, causing brittle failure under sustained loads at low stresses. Emphasis ours.

In describing his invention, Clark states:

The present invention is applicable to the melting and pouring of titanium alloys generally, where contamination is a problem. It is applicable to the melting of commercially pure
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