Hercules Inc. v. Exxon Corp.
Decision Date | 29 July 1980 |
Docket Number | Civ. A. No. 3439. |
Citation | 497 F. Supp. 661 |
Parties | HERCULES INCORPORATED, Plaintiff, v. EXXON CORPORATION, Defendant. |
Court | U.S. District Court — District of Delaware |
COPYRIGHT MATERIAL OMITTED
David F. Anderson of Potter, Anderson & Corroon, Wilmington, Del., for plaintiff; Caspar C. Schneider, Jr., Stanley L. Amberg, William J. Hone, Richard P. Ferrara, and Deborah A. Brandstater of Davis, Hoxie, Faithfull & Hapgood, New York City, of counsel.
Arthur G. Connolly, Jr. of Connolly, Bove & Lodge, Wilmington, Del., for defendant; Thomas F. Reddy, Jr., Berj A. Terzian, Jonathan A. Marshall, and Ronald A. Bleeker of Pennie & Edmonds, New York City, Lee Chasan of Exxon Chemical Co., of counsel.
In this action, Hercules Incorporated ("Hercules") charges Exxon Corporation ("Exxon")1 with infringing both literally and under the Doctrine of Equivalents, United States Patent 3,211,709 which covers a form of sulfur-vulcanizable ethylene propylene terpolymers ("EPT's") useful as synthetic rubbers.2 Hercules's interest in this patent arises by virtue of an assignment from Great Britain's Dunlop Rubber Company, Ltd. ("Dunlop") whose interest in turn is derived from an assignment by its three employees, Drs. Stephen Adamek, Edward Allen Dudley and Raymond Woodhams ("Adamek et al.") whom the patent lists as inventors. Exxon defends by charging that some, if not all, of the claims of the Adamek et al. patent are invalid because (1) the patent involves an obvious development; (2) its disclosure is inadequate; and (3) it was procured by fraud. It is the opinion of this Court that some of Adamek et al.'s involved claims are invalid because Adamek et al.'s disclosures are inadequate. The remaining involved claims, although valid, are not infringed by Exxon's products.
Hercules charges Exxon with infringing Adamek et al. patent claims 1-2, 4-7, 10, 13-14 and 16-183 of which claims 1 and 17 are representative:
Claim 1 (which typifies claims 1-2, 4-7, 10 and 16) and claim 17 (which typifies claims 13-14 and 17-18), thus cover terpolymers containing three hydrocarbons, at least two of which must be alpha-olefins,5 including especially ethylene6 and propylene.7 Adamek et al.'s terpolymers must also contain a bridged-ring polyolefin.8 The essential difference between claim 1 and claim 17 is that while claim 1 broadly specifies the use of a large group of bridged ring polyolefins, claim 17 narrowly specifies the use of only one dicyclopentadiene ("DCP").9
During polymerization, at least one double bond from each olefin becomes a single bond, releasing two electrons-one to each previously doubly bonded carbon atom. These electrons form the single bonds through which the two previously doubly bonded carbon atoms become incorporated within the main chain of the polymer. Ethylene, for instance, polymerizes in this fashion, known as "head-to-tail" or "1,2-" addition:10
Bridged-ring polyolefins are added to the polymer in order to make it curable. Curing refers to a treatment by which rubber is stiffened from a putty-like compound into a harder more resilient and useful material:
Curing is successful when it significantly increases a polymer's stiffness or resistance to stretching. Stiffness is measured by hanging weights from a molded ring of polymeric material and measuring the resulting elongation.13
Curing is usually accomplished by incorporating cross-links of sulfur. Sulfur curing requires the presence of double bonds, which the curing process converts to single bonds. Hence, the need for using polyolefins which, by definition, contain at least two double bonds. The theory is that a polyolefin will sacrifice one of its double bonds for polymerization. The remaining double bonds will remain, providing sites for sulfur vulcanization.14
During World War II, Japan cut off the Allies' traditional sources of natural rubber.15 This caused a massive Allied research program to develop a synthetic substitute.16 For reasons of security, this program was centered among the American rubber companies;17 as a result, American rubber makers developed their technology far in advance of their foreign counterparts, including Dunlop.18 In its subsequent efforts to catch up with the American technology, Dunlop established the North American Research Center ("N.A.R. C.") in Toronto, Canada about 1950.19 About 1954, N.A.R.C. hired Drs. Raymond Woodhams, Stephen Adamek and Edward Allan Dudley,20 who together set out to make the invention involved in this suit.
Adamek, Dudley and Woodhams began their work during the fall of 1956, when they homopolymerized several olefins. They also copolymerized ethylene and propylene,21 and soon they began searching for a suitable diene to polymerize with ethylene and propylene.22 They initially investigated isoprene and butadiene, but when this research proved unfruitful, they considered other dienes including DCP.23
The idea of using DCP may have originated with Dudley, who remembered that in June, 1956, Enjay advertised 24
The idea of using bridged ring structures such as DCP may also have originated with Woodhams who attended a September, 1956 meeting of the American Chemical Society in Atlantic City, New Jersey, where he listened to a lecture by three E. I. du Pont de Nemours & Company ("Du Pont") employees discussing the preparation of homopolymers of norbornene.25 Woodhams thought that norbornene, which closely resembles DCP's bridged-ring,26 "would be a useful monomer to incorporate in our screening program."27
On April 26, 1957, Adamek et al. began preparing and testing EPT's containing numerous third monomer candidates including two bridged-ring dienes-DCP and norbornadiene28 — and a variety of other compounds.29 Only those experiments with the bridged-ring dienes proved successful.30
Adamek et al. then prepared a "rough draft for patent application"31 which they sent on June 12, 1957 to Dunlop's Patent Department in Birmingham, England.32 From this draft, Dunlop's Patent Department prepared a patent application and filed it in Great Britain on July 17, 1957.33 On July 14, 1958, Adamek et al. filed an American application,34 claiming the benefit of their British filing date under 35 U.S.C. § 119.
The American Patent Examiners initially rejected all of Adamek et al.'s claims.35 Dunlop attempted to meet these objections,36 but was unable to do so37 prior to its November 30, 1961 assignment of the Adamek et al.'s American rights to Hercules.38 Hercules's Edwin H. Dafter then assumed responsibility for Adamek et al.'s application. Dafter immediately cancelled all claims then on file and submitted a new set.39 At about the same time, Dafter copied claims from and requested an interference40 with U.S. Patent 3,000,866, which had previously issued, on September 19, 1961, to Du Pont's Robert Edward Tarney.41 The Patent Office granted this request42 and Hercules's interference expert Clinton F. Miller43 assumed responsibility for its prosecution.44 On or about July 16, 1964, the interference terminated in favor of Adamek et al.45 Adamek et al.'s patent eventually issued on October 12, 1965.46
During Hercules's prosecution of Adamek et al.'s application, Exxon began making EPT's47 containing methylene norbornene ("MNB")48 and ethylidene...
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